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SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 10/08/2004 Date Updated: 04/02/2004 Version 1.3 Section 1 - Product and Company Information Product Name VANILLIN, 99% Product Number V1104 Brand ALDRICH Company Sigma-Aldrich Street Address 3050 Spruce Street City, State, Zip, Country SAINT LOUIS MO 63103 US Technical Phone: 314 771 5765 Emergency Phone: 414 273 3850 Ext. 5996 Fax: 800 325 5052 Section 2 - Composition/Information on Ingredient Substance Name CAS # SARA 313 VANILLIN 121-33-5 No Formula C8H8O3 Synonyms m-Anisaldehyde, 4-hydroxy- * Benzaldehyde, 4-hydroxy-3-methoxy- * p-Hydroxy-m-methoxybenzaldehyde * 4-Hydroxy-3-methoxybenzaldehyde * Lioxin * 3-Methoxy-4-hydroxybenzaldehyde * Methylprotocatechuic aldehyde * Protocatechualdehyde, methyl- * Vanilla * Vanillaldehyde * Vanillic aldehyde * p-Vanillin * Vanilline * Zimco RTECS Number: YW5775000 Section 3 - Hazards Identification EMERGENCY OVERVIEW Harmful. Harmful if swallowed. Caution: Avoid contact and inhalation. HMIS RATING HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 1 NFPA RATING HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 1 For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. EYE EXPOSURE In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 6 - Accidental Release Measures PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR