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SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 10/08/2004
Date Updated: 04/02/2004
Version 1.3
Section 1 - Product and Company Information
Product Name VANILLIN, 99%
Product Number V1104
Brand ALDRICH
Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
VANILLIN 121-33-5 No
Formula C8H8O3
Synonyms m-Anisaldehyde, 4-hydroxy- * Benzaldehyde,
4-hydroxy-3-methoxy- *
p-Hydroxy-m-methoxybenzaldehyde *
4-Hydroxy-3-methoxybenzaldehyde * Lioxin *
3-Methoxy-4-hydroxybenzaldehyde *
Methylprotocatechuic aldehyde *
Protocatechualdehyde, methyl- * Vanilla *
Vanillaldehyde * Vanillic aldehyde * p-Vanillin *
Vanilline * Zimco
RTECS Number: YW5775000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Harmful.
Harmful if swallowed.
Caution: Avoid contact and inhalation.
HMIS RATING
HEALTH: 1
FLAMMABILITY: 0
REACTIVITY: 1
NFPA RATING
HEALTH: 1
FLAMMABILITY: 0
REACTIVITY: 1
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Do not breathe dust. Avoid contact with eyes,
skin, and clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep tightly closed.
SPECIAL REQUIREMENTS
Air, light, and moisture sensitive.
ALDRICH - V1104 www.sigma-aldrich.com Page 2
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Government approved respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
Section 9 - Physical/Chemical Properties
Appearance Physical State: Solid
Color: Faintly yellow
Property Value At Temperature or Pressure
Molecular Weight 152.15 AMU
pH N/A
BP/BP Range 170